慢刀伺服车削刀具半径定向补偿的分段逼近求解

复杂曲面的慢刀伺服车削加工过程中，采用刀具法向补偿算法会在各个直线轴产生补偿量，加工法向矢量突变的曲面时，这种算法并非最优，将补偿量只应用于负载较低的直线轴却是更优的选择。提出一种基于线段逼近的刀具半径定向补偿数值求解算法来求解定向刀位点，通过半径细分的策略使法向误差收敛。算法实例验证及与相关算法的对比结果显示，该算法适用于点云构成的曲面或分段曲面的刀具半径补偿。     

基于修正等速运动规律的自由曲面多轴加工刀轴序列优化方法

针对自由曲面多轴加工中起始位置处刀具相对工件速度、加速度不为零导致的一定程度刚性冲击现象,提出了一种基于修正等速运动规律的刀轴序列优化方法,通过控制工件坐标系中决定刀具姿态的两个约束角,使之变化遵循修正等速运动规律,获得了切削行上平稳变化的刀轴序列,避免了由于起始位置处刀具相对工件速度、加速度不为零导致刀具不能精准到达后续加工位置的现象。算例分析表明,该方法能产生平稳且光滑的刀轴序列,可一定程度改善机床运动性能,提高加工表面质量。     

Corrosion behaviour of Mg-Gd-Y-Zn-Ag alloy components with different sizes after cooling

The corrosion behaviour of Mg-6Gd-3Y-1Zn-0.3Ag (wt.%) alloy components with different sizes after cooling was investigated. The alloys in the small components (SC) cooled fast, which were composed of α-Mg matrix and coarse long-period stacking ordered (LPSO) phases. The alloys in the large components (LC) cooled slowly, and there were thin lamellar LPSO phases precipitating inside the grains, except for α-Mg matrix and coarse LPSO phases. The hydrogen evolution test revealed that the corrosion rate of LC sample was higher than that of SC sample. Electrochemical impedance spectroscopy (EIS) test showed that the surface film on LC alloys provided worse protection. The corrosion morphologies indicated that the precipitation of the thin lamellar LPSO phases in LC sample caused severe micro-galvanic corrosion, which accelerated the rupture of the surface film.     

Salt-assisted solution combustion synthesis of NiFe2O4: Effect of salt type

The effects of three types of salt including NaF, KCl, and NaCl on the properties of NiFe₂O₄ nanoparticles using salt-assisted solution combustion synthesis (SSCS) have been investigated. The synthesized powders were evaluated by SEM, TEM, FTIR, XRD, and VSM analysis. Also, the specific surface area (SSA), as well as size distribution and volume of the porosities of NiFe₂O₄ powders were determined by the BET apparatus. The visual observations showed that the intensity and time of combustion synthesis of nanoparticles have been severely influenced by the type of salt. The highest crystallinity was observed in the synthesized powder using NaCl. The SSA has also been correlated completely to the type of salt. The quantities of SSA was achieved about 91.62, 64.88, and 47.22 m²g^-1 for the powders synthesized by KCl, NaCl, and NaF respectively. Although the magnetic hysteresis loops showed the soft ferromagnetic behavior of the NiFe₂O₄ nanoparticles in all conditions, KCl salt could produce the particles with the least coercivity and remanent magnetization. Based on the present study, the salt type is a key parameter in the SSCS process for the preparation of spinel ferrites. Thermodynamic evaluation also showed that the melting point and heat capacity are important parameters for the proper selection of the salt.     

响应面法优化α-淀粉酶的酶反应体系

目的:采用单因素实验及响应面法优化α-淀粉酶的反应体系。方法:以淀粉为底物对象，以可溶性淀粉浓度、α-淀粉酶浓度、反应时间为考察因素，在单因素实验基础上，运用Box-behnken实验设计方法研究各因素及其交互作用对α-淀粉酶作用底物时的反应速度的影响。结果:建立α-淀粉酶酶反应体系的最佳反应条件为12.0 mg/mL可溶性淀粉、1.50 U/mL α-淀粉酶、10.0 min反应时间，在此条件下，α-淀粉酶表现出的反应速度达到（19.53±1.74） mmol/（L·min），接近模型中的预测数值18.75 mmol/（L·min）。结论:此优化α-淀粉酶酶反应体系的方法可行，能够使α-淀粉酶在反应过程中发挥的酶活最大化，为日后在此体系下进行糖苷酶抑制剂的研究奠定了基础，具有一定的指导意义。     

Poly(ether-block-amide) membrane with deformability and adjustable surface hydrophilicity for water purification

Freshwater resources are currently insufficient, and another form of freshwater resources, namely, ice, is very interesting except for the issue of how to use new materials for effective purification during the processing procedure. In this article, a new membrane material with multisize pore structure in the cross-section and intact thin skin layer on the upper and lower surfaces was successfully prepared by adding porogen, filler and setting heating environment during the phase separation process. The membrane exhibits excellent axial deformability, and its elongation at break can reach to 160% strain. Meanwhile, they all show elastic deformation behavior in the range from −60 to 100°C. Even if high content of hydrophobic filler is compounded into these membranes, that is, 5.7 wt% carbon tube content, water contact angle of membrane's surface is only 72.5°, demonstrating obvious hydrophilicity. In addition, in the water purification process, the adsorption rate constant reached ideal value of 0.26 s⁻¹, and the equilibrium adsorption capacity was about 2.8 g/g, showing fast and efficient water purification ability. In the mode of external heating source or the membrane's heat dissipation, these prepared membranes can melt the ice to obtain purified water and exhibit a controllable purification ability in this process.     

Position-varying surface roughness prediction method considering compensated acceleration in milling of thin-walled workpiece

Machined surface roughness will affect parts’ service performance. Thus, predicting it in the machining is important to avoid rejects. Surface roughness will be affected by system position dependent vibration even under constant parameter with certain toolpath processing in the finishing. Aiming at surface roughness prediction in the machining process, this paper proposes a position-varying surface roughness prediction method based on compensated acceleration by using regression analysis. To reduce the stochastic error of measuring the machined surface profile height, the surface area is repeatedly measured three times, and Pauta criterion is adopted to eliminate abnormal points. The actual vibration state at any processing position is obtained through the single-point monitoring acceleration compensation model. Seven acceleration features are extracted, and valley, which has the highest R-square proving the effectiveness of the filtering features, is selected as the input of the prediction model by mutual information coefficients. Finally, by comparing the measured and predicted surface roughness curves, they have the same trends, with the average error of 16.28% and the minimum error of 0.16%. Moreover, the prediction curve matches and agrees well with the actual surface state, which verifies the accuracy and reliability of the model.     

Process parameter dependencies of continuous and pulsed laser modes on surface polishing of additive manufactured aluminium AlSi10Mg parts

Laser powder bed fusion is a well-established 3D printing technique for metal alloys, but exhibits a poor surface quality. Laser polishing provides the possibility of a fast contact-free and fully-automatable surface treatment. This paper deals with the experimental investigation of laser polishing of laser powder bed fusion parts made of aluminium AlSi10Mg. Laser polishing is done with a 4 kW solid state disc laser in combination with a multi-axis system and a one dimensional scanner optic. The laser is operated at continuous and pulsed operation mode. The parameter study reveals a high dependency of the achievable roughness on the laser beam intensity, the track and pulse overlap, the energy density and the number of polishing passes and polishing directions. Pulsed laser polishing mode with up to four passes from different directions revealed the lowest surface roughness of 0.14 μm Ra. With respect to the initial average surface roughness of Ra = 8.03 μm a reduction of the surface roughness of greater than 98 % could be achieved. Polishing with continuous laser radiation at one polishing pass resulted in Ra = 0.23 μm at an area rate of 20 cm²/min. Laser polishing using four passes achieved a further improvement up to Ra = 0.14 μm.     

Enhanced photocatalytic H2 evolution over In2S3 via decoration with GO and Fe2P co-catalysts

In this study, GO and Fe₂P were used as co-catalysts to improve the separation efficiency of photogenerated electron-hole pairs in an In₂S₃ photocatalyst. The metallic character of Fe₂P provided a cheap substitute for traditional noble metal co-catalyst for H₂ production in aqueous media. The GO/Fe₂P/In₂S₃ composite demonstrated significantly enhanced photocatalytic activity compared to pure In₂S₃, delivering a H₂ production rate of 483.35 μmol h^?1 g^?1 and a quantum yield was 22.68% under visible light irradiation. The design of the photocatalyst was optimized using “Design Expert” software. The analysis showed that a GO loading of 1.18 wt%, a Fe loading of 5.36 wt%, and a calcination temperature of 180 °C were optimal.